HuagongsheHuagongshe Chemistry Print Report · For research reference only
Cyclopentadiene → Santene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Cyclopentadiene | HCID 7612 | — |
| Reactant | Bicyclo(2.2.1)heptane | HCID 9233 | — |
| Reactant | But-2-ene | HCID 12220 | — |
| Product | Santene | HCID 10720 | — |
| Product | 3-Methyl-2-methylenenorbornane | HCID 12304420 | — |
Reaction Steps
The method of the invention to give the bicyclo[2.2.1]heptane derivatives in one step comprises reacting 2-butene with cyclopentadiene in the presence of an isomerization catalyst for simultaneous isomerization to give 2-methylene-3-methylbicyclo[2.2.1]heptane and/or 2,3-dimethylbicyclo[2.2.1]hept-2-ene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06841713B2 |
| Source dataset | uspto-grants-2005_01 |
| ORD ID | ord-5a57280c6e2c48e68a502afd3c07face |
| Source note | uspto-grants-2005_01 |