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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1762065Generated: October 30, 2026

Benzene → Ethylbenzene

https://huagongshe.com/reaction/1762065

Reaction equation

Participants

RoleNameHCIDCharge
ReactantBenzeneHCID 241—
ReactantOctaneHCID 356—
ReactantHexaneHCID 8058—
CatalystPlatinumHCID 23939—
SolventTolueneHCID 1140—
SolventO-XyleneHCID 7237—
SolventHeptaneHCID 8900—
ProductEthylbenzeneHCID 7500—
Product2-MethylheptaneHCID 11594—

Reaction Steps

A standard test (based on hexane conversion at 1000° F.) indicated a hexane conversion activity between 200 and 500, with a very high benzene selectivity (60%). At very high hexane conversions (99%), benzene was formed in over 94% yield. Similarly, n-heptane yielded 96% toluene. Similarly, n-heptane yielded 96% toluene. Consistent with the non-acidic nature of this platinum catalyst, n-octane yielded predominantly ethylbenzene and ortho-xylene, 2-methylheptane produced mostly meta-xylene, and 3-methylheptane formed mainly ethylbenzene, para-, and ortho-xylene.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS04830729
Source datasetuspto-grants-1989_05
ORD IDord-4545dd10341647a9a474f2bf624f2ae0
Source noteuspto-grants-1989_05