Formamide → HCID 178526029, compound

HRID 1762288Notes

Reaction equation

HRID 1762288 reaction equation
[O-2].[O-2].[O-2].[O-2].[O-2].[V+5:6].[V+5].[C:8]([OH:13])(=[O:12])[C:9]([OH:11])=[O:10].C(N)=O>O>[C:8]([O-:13])(=[O:12])[C:9]([O-:11])=[O:10].[V+5:6].[C:8]([O-:13])(=[O:12])[C:9]([O-:11])=[O:10].[C:8]([O-:13])(=[O:12])[C:9]([O-:11])=[O:10].[C:8]([O-:13])(=[O:12])[C:9]([O-:11])=[O:10].[C:8]([O-:13])(=[O:12])[C:9]([O-:11])=[O:10].[V+5:6]

Participants

5

Reactant 3

HCID 713FormamideHCID 971Oxalic AcidHCID 178419084HCID 178419084, compound

Product 1

HCID 178526029HCID 178526029, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A catalyst is prepared following the procedure used to prepare Catalyst A of U.S. Pat. No. 4,582,911: To 40 ml of water is added 0.75 gm vanadium pentoxide, 1.65 gm oxalic acid and 3.75 gm formamide at room temperature with stirring to form vanadium oxalate, and this solution was then mixed with 10.0 gm titanium dioxide anatase powder (which were first dispersed in 20 ml of water). The resulting mixture was heated with stirring at 65° C. to evaporate the majority of the water, followed by drying in an oven (101 kPa) at 110° C. for 16 hours. The resulting solid was then calcined in a flowing oxygen gas stream at 450° C. for 2 hours, followed by crushing and screening to form -20+40 mesh particle sizer. The catalyst formed by the above impregnation procedure was determined by calculation (based on the vanadium salt and the weight of the titanium dioxide particles) to contain 7 wt. % V2O5 on the TiO2.

Workup

  1. customA catalyst is prepared

Sources & evidence

ORD record
ord-33f14cfa0ecb453bb482ab7b9ac78034
Source dataset
uspto-grants-1989_05
Patent number
US04831164

Reaction notes

Loading…