m-(Trifluoromethyl)nitrobenzene → alpha,alpha,alpha-Trifluoro-3-nitro-o-xylene

HRID 1762310Notes

Reaction equation

[N+:1]([C:4]1[CH:5]=[C:6]([C:10]([F:13])([F:12])[F:11])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2].[CH3:14]S(C)(=O)=C>>[CH3:14][C:5]1[C:4]([N+:1]([O-:3])=[O:2])=[CH:9][CH:8]=[CH:7][C:6]=1[C:10]([F:11])([F:12])[F:13]

Participants

Reactant 2

HCID 7386m-(Trifluoromethyl)nitrobenzene

HCID 6396768Dimethylsulfoxonium methylide

Product 1

HCID 81171alpha,alpha,alpha-Trifluoro-3-nitro-o-xylene

Procedure

reacting 3-nitrobenzotrifluoride with dimethyloxosulfonium methylide to produce 2-methyl-3-nitro-benzotrifluoride; and

Sources & evidence

ORD record: ord-e54a02c131b14b8ba9b30ac8599fa536
Source dataset: uspto-grants-1989_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04831193

Reaction notes

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