(4-Amino-3-nitrophenyl)-4-methylphenyl sulfoxide → HCID 53748146, compound

HRID 1762340Notes

Reaction equation

NC1C=CC(C2C=C(C)C=CC=2S(C2C=CC(C)=CC=2C2C=CC(N)=C([N+]([O-])=O)C=2)=O)=CC=1[N+]([O-])=O.[Cl:37][C:38]1[CH:43]=[CH:42][C:41]([S:44][C:45]2[CH:50]=[CH:49][C:48]([C:51]3[C:56]([N+:57]([O-])=O)=[C:55]([NH2:60])[CH:54]=[CH:53][C:52]=3[S:61]([C:63]3[CH:68]=[CH:67][C:66]([NH2:69])=[C:65]([N+:70]([O-])=O)[C:64]=3[C:73]3[CH:78]=[CH:77][C:76]([S:79][C:80]4[CH:85]=[CH:84][C:83]([Cl:86])=[C:82]([N+:87]([O-])=O)[CH:81]=4)=[CH:75][CH:74]=3)=[O:62])=[CH:47][CH:46]=2)=[CH:40][C:39]=1[N+:90]([O-])=O>>[Cl:86][C:83]1[CH:84]=[CH:85][C:80]([S:79][C:76]2[CH:75]=[CH:74][C:73]([C:64]3[C:65]([NH2:70])=[C:66]([NH2:69])[CH:67]=[CH:68][C:63]=3[S:61]([C:52]3[CH:53]=[CH:54][C:55]([NH2:60])=[C:56]([NH2:57])[C:51]=3[C:48]3[CH:49]=[CH:50][C:45]([S:44][C:41]4[CH:42]=[CH:43][C:38]([Cl:37])=[C:39]([NH2:90])[CH:40]=4)=[CH:46][CH:47]=3)=[O:62])=[CH:78][CH:77]=2)=[CH:81][C:82]=1[NH2:87]

Participants

Reactant 2

HCID 53642139(4-Amino-3-nitrophenyl)-4-methylphenyl sulfoxide

HCID 53870024HCID 53870024, compound

Product 1

HCID 53748146HCID 53748146, compound

Procedure

Following the procedure described in Example 40 but using as a starting material instead of (4-amino-3-nitrophenyl)-4-methylphenyl sulfoxide a corresponding amount of [4-(4-chloro-3-nitrophenylthio)-phenyl]-4-amino-3-nitrophenyl sulfoxide, the title compound is obtained.

Sources & evidence

ORD record: ord-11f9fc5c9213423bbfcee7e1bfe0c079
Source dataset: uspto-grants-1989_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04831194

Reaction notes

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