HuagongsheHuagongshe Chemistry Print Report · For research reference only
α-Ethynyl-6-phenoxy-2-pyridinemethanol → 2,2-Dimethyl-3-(3-cyclopropylmethoxy-3-oxo-1-propenyl) cyclopropane-carboxylic acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | α-Ethynyl-6-phenoxy-2-pyridinemethanol | HCID 12800596 | — |
| Reactant | 2,2-Dimethyl-3-(3-cyclopropylmethoxy-3-oxo-1-propenyl) cyclopropane-carboxylic acid | HCID 53915596 | — |
| Product | 2,2-Dimethyl-3-(3-cyclopropylmethoxy-3-oxo-1-propenyl) cyclopropane-carboxylic acid | HCID 53915596 | — |
| Product | 2,2-Dimethyl-3-(3-methoxy-3-oxo-1-propeny)-cyclopropane-carboxylate | HCID 86743070 | — |
Reaction Steps
Using the procedure of Example 9, (1R, cis, ΔZ) 2,2-dimethyl-3-(3-methoxy-3-oxo-1-propenyl)-cyclopropane-carboxylic acid and (R, S) 1-(6-phenoxy-2-pyridinyl)-2-propyn-1-yl alcohol were reacted to obtain (R, S) 1-(6-phenoxy-2-pyridinyl)-2-propyn-1-yl (1R, cis, ΔZ) 2,2-dimethyl-3-(3-methoxy-3-oxo-1-propenyl)-cyclopropane-carboxylate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04833163 |
| Source dataset | uspto-grants-1989_05 |
| ORD ID | ord-fea899a1c6734d62bbf4de33bfa3d6fd |
| Source note | uspto-grants-1989_05 |