HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,8-Diazabicyclo(5.4.0)undec-7-ene → HCID 86743061, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,8-Diazabicyclo(5.4.0)undec-7-ene | HCID 81184 | — |
| Reactant | Magnesium Chloride | HCID 5360315 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | HCID 86743061 | HCID 86743061 | 72.7% |
Reaction Steps
152.2 g (1.0 mole) of DBU and 47.6 g (0.5 moles) of anhydrous MgCl2 were refluxed in 300 g of methanol with heating for 8 hours, and then cooled. The deposited crystals were recovered therefrom by filtration, washed with acetone and dried, whereby 145.2 g of DBU/MgCl2 complex compound was obtained (yield: 72.7%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04833212 |
| Source dataset | uspto-grants-1989_05 |
| ORD ID | ord-5dc7d084903e4debb372b70e13c172c9 |
| Source note | uspto-grants-1989_05 |