HuagongsheHuagongshe Chemistry Print Report · For research reference only
5,7-dihydro-6H-dibenz[c,e]azepine-6carbonitrile → dodecyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-thiocarboximidate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 5,7-dihydro-6H-dibenz[c,e]azepine-6carbonitrile | HCID 19833886 | — |
| Reactant | Sodium dodecane-1-thiolate | HCID 23672953 | — |
| Solvent | 1-Dodecanethiol | HCID 8195 | — |
| Product | dodecyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-thiocarboximidate | HCID 19833911 | — |
Reaction Steps
starting from 5,7-dihydro-6H-dibenz[c,e]azepine-6-carbonitrile and sodium dodecanethiolate in 1-dodecanethiol there is obtained dodecyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-thiocarboximidate, which is purified by flash chromatography on silica gel using n-hexane/ethyl acetate (1:1) as the eluent; 1H-NMR(CDCl3): 0.88 (t, CH3), 1.2-2.0 (20H), 2.5 (t, SCH2), 4.43 (s, 4H), 7.3-7.7 (8H);
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04833245 |
| Source dataset | uspto-grants-1989_05 |
| ORD ID | ord-1ab25af579334810a2729fe8ce0e6a24 |
| Source note | uspto-grants-1989_05 |