1-Butanol → butyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-carboximidate

HRID 1762701Notes

Reaction equation

HRID 1762701 reaction equation
[CH:1]1[C:11]2[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8][N:7]([C:16]#[N:17])[CH2:6][C:5]=2[CH:4]=[CH:3][CH:2]=1.[CH2:18]([OH:22])[CH2:19][CH2:20][CH3:21]>>[CH:1]1[C:11]2[C:10]3[CH:12]=[CH:13][CH:14]=[CH:15][C:9]=3[CH2:8][N:7]([C:16](=[NH:17])[O:22][CH2:18][CH2:19][CH2:20][CH3:21])[CH2:6][C:5]=2[CH:4]=[CH:3][CH:2]=1

Participants

3

Reactant 2

HCID 2631-ButanolHCID 198338865,7-dihydro-6H-dibenz[c,e]azepine-6carbonitrile

Product 1

HCID 20041717butyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-carboximidate

Procedure

starting from 5,7-dihydro-6H-dibenz[c,e]azepine-6-carbonitrile and n-butanol there is obtained butyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-carboximidate as a resinous product, 1H-NMR(CDCl3): 1.02 (t, CH2CH3), 1.4-2.0 (4H), 4.15 (t, OCH2), 4.27 (s, 4H), 4.57 (broad s, NH), 7.3-7.7 (8H);

Sources & evidence

ORD record
ord-e104bf75d2e145d980b2cb4a62138b72
Source dataset
uspto-grants-1989_05
Patent number
US04833245

Reaction notes

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