Chloranil → HCID 20309546, compound

HRID 1763327Notes

Reaction equation

HRID 1763327 reaction equation
[C:1]([NH:5][CH2:6][CH:7]([OH:26])[CH2:8][O:9][C:10]1[CH:18]=[CH:17][C:13]([C:14]([OH:16])=[O:15])=[CH:12][C:11]=1[C:19]1[CH2:24][CH2:23][C:22](=[O:25])[NH:21][N:20]=1)([CH3:4])([CH3:3])[CH3:2].C1(Cl)C(=O)C(Cl)=C(Cl)C(=O)C=1Cl>C(O)CCC>[C:1]([NH:5][CH2:6][CH:7]([OH:26])[CH2:8][O:9][C:10]1[CH:18]=[CH:17][C:13]([C:14]([OH:16])=[O:15])=[CH:12][C:11]=1[C:19]1[CH:24]=[CH:23][C:22](=[O:25])[NH:21][N:20]=1)([CH3:4])([CH3:2])[CH3:3]

Participants

4

Reactant 2

HCID 8371ChloranilHCID 20309526HCID 20309526, compound

Product 1

HCID 20309546HCID 20309546, compound

Reagents, catalysts & solvents 1

HCID 2631-ButanolSolvent

Procedure

A mixture of 4-(3-t-butylamino-2-hydroxypropoxy)-3-(1,4,5,6-tetrahydro-6-oxo-3-pyridazinyl)benzoic acid, chloranil, and n-butanol, was heated under reflux to give 4-(3-t-butylamino-2-hydroxypropoxy)-3-(1,6-dihydro-6-oxo-3-pyridazinyl)benzoic acid.

Workup

  1. temperaturewas heated
  2. temperatureunder reflux

Sources & evidence

ORD record
ord-9a870951e4064700a0bd0a1fbb8a66ea
Source dataset
uspto-grants-1978_09
Patent number
US04111936

Reaction notes

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