Dichloromethane → HCID 13363448, compound

Participants

Reaction Steps

To a solution of 16.0g of N-methyl-N-chlorosulfenyl carbamoyl chloride in 100 ml of methylene chloride was added 12.0g of methallyl chloride with stirring, at room temperature. On slight heating there was a spontaneous exotherm which raised the temperature of the reaction mixture to 39° C. On removal of the solvent under reduced pressure 19.6g of oil was obtained. nD25 1.5379. Infra-red (neat) 5.76 (C=O), 8.0, 8.65, 9.8, 11.8, 12.25, 13.45 and 14.0μ. NMR(CDCl3) δ 1.41 (s), 3H; 3.48 (s), 3H; 3.87 (d). JAB = 12.0 HZ and 3.97 (d), JBA = 12.0 HZ 4H. Calc'd. for C6H10Cl3NOS: C, 28.76; H, 4.02; N, 5.59. Found: C, 28.87; H, 3.87; N, 4.72.

Provenance & Evidence