HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dichloromethane → N-Methyl-N-(2-methyl-1,3-dichloro-2-propanesulfenyl)carbamoyl fluoride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dichloromethane | HCID 6344 | — |
| Reactant | 3-Chloro-2-methyl-1-propene | HCID 11241 | — |
| Reactant | N-chlorothio(methyl)carbamoyl fluoride | HCID 12922862 | — |
| Product | N-Methyl-N-(2-methyl-1,3-dichloro-2-propanesulfenyl)carbamoyl fluoride | HCID 54204012 | — |
Reaction Steps
To a solution of 1.35g of methallyl chloride in 25 ml of methylene chloride was added 2.15g of N-methyl-N-chlorosulfenyl carbamoyl fluoride. The solution was heated to reflux for 45 min. and concentrated to 1.68g of pale yellow oil. Infra-red (neat) 5.57 (C=O), 6.9, 7.0, 7.26, 7.65, 8.45, 9.15, 10.42, 12.3, 13.3 and 14.1μ. NMR (CDCl3) δ 1.39 (s), 3H; 3.36 (d), J = 1.0 HZ, 3H, 3.92 (s), 4H.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04111989 |
| Source dataset | uspto-grants-1978_09 |
| ORD ID | ord-bc0eb5e9661b4c3083fb5bf1b04aaab0 |
| Source note | uspto-grants-1978_09 |