HCID 20310588, compound → HCID 54379087, compound

HRID 1763668Notes

Reaction equation

HRID 1763668 reaction equation
[CH:1]([C:3]1[CH:4]=[C:5]2[N:11]([CH:12]=1)[CH:10]=[CH:9][C:8]1[CH:13]=[CH:14][CH:15]=[CH:16][C:7]=1[C:6]2=O)=[O:2].[CH:18]([C:20]1[CH:34]=[CH:33][C:23]2[CH2:24][CH2:25][N:26]3[CH:32]=[CH:31][CH:30]=[C:27]3[C:28](=O)[C:22]=2[CH:21]=1)=[O:19].C([C:37]1[CH:51]=[CH:50][C:40]2[CH:41]=[CH:42][N:43]3[CH:49]=[CH:48][CH:47]=[C:44]3[C:45](=O)[C:39]=2[CH:38]=1)=O>>[CH:1]([C:3]1[CH:4]=[C:5]2[N:11]([CH:12]=1)[CH:10]=[CH:9][C:8]1[CH:13]=[CH:14][CH:15]=[CH:16][C:7]=1[C:6]2=[CH:23][CH2:24][CH2:25][N:26]([CH3:32])[CH3:27])=[O:2].[CH:18]([C:20]1[CH:34]=[CH:33][C:23]2[CH2:24][CH2:25][N:26]3[CH:32]=[CH:31][CH:30]=[C:27]3[C:28](=[CH:40][CH2:41][CH2:42][N:43]([CH3:49])[CH3:44])[C:22]=2[CH:21]=1)=[O:19].[CH3:5][N:11]([CH3:12])[CH2:10][CH2:9][CH:8]=[C:45]1[C:39]2[CH:38]=[CH:37][CH:51]=[CH:50][C:40]=2[CH:41]=[CH:42][N:43]2[CH:49]=[CH:48][CH:47]=[C:44]12

Participants

6

Reactant 3

HCID 20310588HCID 20310588, compoundHCID 20310600HCID 20310600, compoundHCID 20310627HCID 20310627, compound

Product 3

HCID 54379087HCID 54379087, compoundHCID 54443558HCID 54443558, compoundHCID 86735991HCID 86735991, compound

Procedure

Using substantially the same procedure as in Example XXII, Steps A, B, and C (the present example) but starting with 2-formyl-11H-pyrrolo[2,1-b][3]benzazepin-11-one, 6,11-dihydro-9-formyl-5H-pyrrolo[2,1-b][3]benzazepin-11-one, or 9-formyl-11H-pyrrolo[2,1-b][3]benzazepin-11-one, there is obtained 2-formyl-11-(3-dimethylaminopropylidene)-11H-pyrrolo[2,1-b][3]benzazepine, 9-formyl-11-(3-dimethylaminopropylidene)-6,11-dihydro-5H-pyrrolo[2,1-b][3]benzazepine, or 9-formyl-11-(3-dimethylaminopropylidene-11H-pyrrolo[2,1-b][3]benzazepine, respectively.

Sources & evidence

ORD record
ord-05320971cc134259a578aba48c331a9b
Source dataset
uspto-grants-1978_09
Patent number
US04112112

Reaction notes

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