Formaldehyde → 3-Cyclohexene-1,1-dimethanol

HRID 1763798Notes

Reaction equation

HRID 1763798 reaction equation
[CH:1](=[O:8])[CH:2]1[CH:7]=[CH:6][CH2:5][CH2:4][CH2:3]1.[CH2:9]=[O:10]>>[C:2]1([CH2:9][OH:10])([CH2:1][OH:8])[CH2:3][CH2:4][CH:5]=[CH:6][CH2:7]1

Participants

3

Reactant 2

HCID 712FormaldehydeHCID 109313902-Cyclohexene-1-carbaldehyde

Product 1

HCID 165443-Cyclohexene-1,1-dimethanol

Procedure

The further reaction of the tetrahydrobenzaldehyde with surplus formaldehyde to form 3-cyclohexene-1,1-dimethanol and its derivatives has already been reported by H. E. French and D. M. Gallagher in J. Amer. Chem. Soc. 64, pages 1497-99 (1942). ##STR10##

Sources & evidence

ORD record
ord-33638e7326a54ce1b1216c31bca9cddf
Source dataset
uspto-grants-1978_09
Patent number
US04113664

Reaction notes

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