Acetone → HCID 86736016, compound

HRID 1763889Notes

Reaction equation

HRID 1763889 reaction equation
C(=O)([O-])[O-:2].[Ca+2:5].[OH2:6].[S:7](=[O:9])=[O:8].[CH3:10][C:11]([CH3:13])=[O:12]>>[OH2:2].[OH:12][C:11]([S:7]([O-:6])(=[O:9])=[O:8])([CH3:13])[CH3:10].[Ca+2:5].[OH:12][C:11]([S:7]([O-:2])(=[O:9])=[O:8])([CH3:13])[CH3:10]

Participants

5

Reactant 4

HCID 180AcetoneHCID 962WaterHCID 1119Sulfur DioxideHCID 10112Calcium Carbonate

Product 1

HCID 86736016HCID 86736016, compound

Procedure

Pure calcium 2-hydroxy-2-propanesulfonate monohydrate was prepared by reacting 40 g of calcium carbonate with 114 g of water, 86 g of acetone and excess sulfur dioxide for 3 hours at 25° C. The reaction mixture was filtered, and the white solids washed with 50 ml of acetone, then with ether, then air dried for 30 minutes and chemically analyzed. Calculated for Ca[(CH3)2C(OH)SO3 ]2 ·H2O: Ca 11.9 percent, C 21.4 percent, H 4.8 percent, S 19.1 percent; observed: Ca 12.2 percent, C 21.0 percent, H 4.3 percent, S 18.8 percent.

Workup

  1. customfor 3 hours
  2. customat 25° C
  3. filtrationThe reaction mixture was filtered
  4. washthe white solids washed with 50 ml of acetone
  5. dry with materialwith ether, then air dried for 30 minutes

Sources & evidence

ORD record
ord-f00b0fbf1f264a779dedc69aa748f71c
Source dataset
uspto-grants-1978_09
Patent number
US04113842

Reaction notes

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