Acetic Acid → HCID 20308575, compound

HRID 1763902Notes

Reaction equation

HRID 1763902 reaction equation
[CH3:1][CH:2]=[CH:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20].C(O)(=[O:23])C.[OH-].[Na+]>C(OO)(=O)C.O>[O:23]1[CH:3]([CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])[CH:2]1[CH3:1]

Participants

6

Reactant 3

HCID 176Acetic AcidHCID 14798Sodium HydroxideHCID 5274512-eicosene (Z)

Product 1

HCID 20308575HCID 20308575, compound

Reagents, catalysts & solvents 2

HCID 962WaterSolventHCID 6585Peracetic AcidSolvent

Procedure

7 g of 2-eicosene are dissolved in 20 g of peracetic acid. The ethylenic function is oxidised into epoxide in the absence of heat. The acetic acid formed is neutralised in 10 ml of water by the addition of 1N NaOH. The aqueous solution thus obtained is extracted with ether. Removal of the ether leaves 6 g of 2,3-epoxy eicosane which is purified in the same way as described above. Mp: 40° C., bp 15 mm Hg : 200°-210° C.

Workup

  1. temperatureof heat
  2. customThe aqueous solution thus obtained
  3. extractionis extracted with ether
  4. customRemoval of the ether

Sources & evidence

ORD record
ord-f9e1b43f774e4da7842d1321b2245b2d
Source dataset
uspto-grants-1978_09
Patent number
US04113875

Reaction notes

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