Hydrochloric Acid → HCID 178434702, compound

Participants

Reaction Conditions

Reaction Steps

##STR7## 1-Phenyl-1-propyne (2.52 g) and azidotrimethylsilane (2.48 g, Me3SiN3) were sealed into a heavy-walled glass reactor at -70° C. and 0.5 mm Hg. The mixture was heated 11 days at 155° C., cooled, dissolved in diethyl ether (Et2O), and stirred briefly with 5 percent HCl. After washing with a small amount of NaHCO3 solution, the Et2O solution was evaported to give 3.06 g (89%) cream white solid, mp 173.5-174.0 whose NMR spectrum and elemental analysis confirm its structure.

Provenance & Evidence