HuagongsheHuagongshe Chemistry Print Report · For research reference only
Bromide ion → 2-Bromo-4'-azido-2',3',5',6'-tetrafluoroacetophenone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Bromide ion | HCID 259 | — |
| Reactant | Sodium Azide | HCID 33557 | — |
| Reactant | 2',3',4',5',6'-Pentafluoroacetophenone | HCID 69546 | — |
| Product | 2-Bromo-4'-azido-2',3',5',6'-tetrafluoroacetophenone | HCID 14642570 | — |
Reaction Steps
Compound 151 was prepared using the following strategy. 2′,3′,4′,5′,6′-Pentafluoroacetophenone, A6 was treated with sodium azide, followed by bromide, to provide 2-bromo-4′-azido-2′,3′,5′,6′-tetrafluoroacetophenone, A151 (Keana, J. F. W.; Cai, S. X. J. Org. Chem., 1990, 55, 3640).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07230019B2 |
| Source dataset | uspto-grants-2007_06 |
| ORD ID | ord-aae71c647ac94972a186cc9d11220332 |
| Source note | uspto-grants-2007_06 |