Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Glycerol | HCID 753 | — |
| Reactant | Water | HCID 962 | — |
| Reactant | Potassium Hydroxide | HCID 14797 | — |
| Reactant | HCID 178506433 | HCID 178506433 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 178506435 | HCID 178506435 | 73.4% |
Reaction Steps
To a 3 necked round bottom flask 0.2 g (438.6 mmol) of 9-(4-fluoro-phenyl)-thianthrenium hexafluorophosphate and 10 g of glycerol were added. The suspension was stirred at 120° C. until complete dissolution. Then 50 mg of potassium hydroxide were added and stirred for 10 minutes and the mixture was poured into water. Dichloromethane was added and the organic layer was washed and dried (Na2SO4). Removal of the solvent under vacuum gave a white solid (0.17 g, 73.4%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US07230121B2 |
|---|
| Source dataset | uspto-grants-2007_06 |
|---|
| ORD ID | ord-dfa61809de284a51a35bfaa7ac664988 |
|---|
| Source note | uspto-grants-2007_06 |
|---|
