1-Iodo-4-propylbenzene → HCID 178506682, compound

HRID 1768877Notes

Reaction equation

HRID 1768877 reaction equation
[CH2:1]([C:4]1[CH:9]=[CH:8][C:7](I)=[CH:6][CH:5]=1)[CH2:2][CH3:3].C([Li:15])CCC>CCCCCC>[CH2:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[Li:15])[CH2:2][CH3:3]

Participants

4

Reactant 2

HCID 6125411-Iodo-4-propylbenzeneHCID 178418339Butyllithium

Product 1

HCID 178506682HCID 178506682, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent3×

Procedure

Air in a dried four-necked flask was replaced with nitrogen, and 10 ml of n-hexane and 2.86 g (0.0116 mol) of p-n-propyliodobenzene were introduced. Then, 10 ml of a hexane solution of n-butyl lithium (0.0116 mol) was gradually added thereto under stirring to obtain a hexane solution of n-propylphenyl lithium.

Workup

  1. additionwere introduced

Sources & evidence

ORD record
ord-4b190226ff2742a6b1d07963b1a1915f
Source dataset
uspto-grants-1995_01
Patent number
US05380461

Reaction notes

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