Ethyl 5-bromofuran-2-carboxylate → HCID 15229191, compound

HRID 1769324Notes

Reaction equation

HRID 1769324 reaction equation
[CH3:1][C:2]1([CH3:14])[C:11]2[C:6](=[CH:7][CH:8]=[C:9]([C:12]#[CH:13])[CH:10]=2)[S:5][CH2:4][CH2:3]1.Br[C:16]1[O:20][C:19]([C:21]([O:23][CH2:24][CH3:25])=[O:22])=[CH:18][CH:17]=1>>[CH2:24]([O:23][C:21]([C:19]1[O:20][C:16]([C:13]#[C:12][C:9]2[CH:10]=[C:11]3[C:6](=[CH:7][CH:8]=2)[S:5][CH2:4][CH2:3][C:2]3([CH3:14])[CH3:1])=[CH:17][CH:18]=1)=[O:22])[CH3:25]

Participants

3

Reactant 2

HCID 345282Ethyl 5-bromofuran-2-carboxylateHCID 109325396-Ethynyl-4,4-dimethylthiochroman

Product 1

HCID 15229191HCID 15229191, compound

Procedure

Again using the general procedure of Example 11, but using instead 4,4-dimethyl-6-ethynylthiochroman and ethyl 5-bromo-2-furate, the title compound was synthesized.

Sources & evidence

ORD record
ord-af6b73cd6f584e2facb02d5c6ee77168
Source dataset
uspto-grants-1995_01
Patent number
US05380877

Reaction notes

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