HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → Silane, [(4-bromophenyl)methoxy](1,1-dimethylethyl)diphenyl-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | 4-Bromobenzyl alcohol | HCID 70119 | — |
| Reactant | tert-Butyldiphenylchlorosilane | HCID 94078 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | Silane, [(4-bromophenyl)methoxy](1,1-dimethylethyl)diphenyl- | HCID 14903624 | — |
Reaction Steps
To a stirred solution of 7.48 g (40 mmoles) of p-bromobenzyl alcohol and 6.07 g (60 mmoles) of triethylamine in 70 mL of sieve dried DMF at 0° C. was added 14.3 g (52 mmoles) of neat t-butyldiphenylsilylchloride. The ice-water bath was removed and the mixture was stirred further for 20 hours.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05384317 |
| Source dataset | uspto-grants-1995_01 |
| ORD ID | ord-5228b6acfaa54e299bcd1269842ee54a |
| Source note | uspto-grants-1995_01 |