Aluminium lithium hydride → HCID 21253605, compound

HRID 1770305Notes

Reaction equation

HRID 1770305 reaction equation
[H-].[Al+3].[Li+].[H-].[H-].[H-].[C:7]([C:9]1[CH:24]=[CH:23][C:12]([CH2:13][O:14][C:15]([C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=2)=[CH2:16])=[CH:11][CH:10]=1)#[N:8]>>[NH2:8][CH2:7][C:9]1[CH:24]=[CH:23][C:12]([CH2:13][O:14][C:15]([C:17]2[CH:18]=[CH:19][CH:20]=[CH:21][CH:22]=2)=[CH2:16])=[CH:11][CH:10]=1

Participants

3

Reactant 2

HCID 21226445Aluminium lithium hydrideHCID 21253630HCID 21253630, compound

Product 1

HCID 21253605HCID 21253605, compound

Procedure

Lithium aluminium hydride reduction of α-(4-cyanobenzyloxy)styrene led to this compound: 1H NMR (CD3OD) δ 3.73 (2H, br s), 4.30 (1H, d, J 3 Hz), 4.70 (1H, d, J 3 Hz), 4.72 (2H, s), 4.87 (2H, s), 7.1-7.7 (9H, m).

Sources & evidence

ORD record
ord-22cdd8b66b264f5aacb915a71eea496a
Source dataset
uspto-grants-1995_01
Patent number
US05385996

Reaction notes

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