HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methane → 3-Phenyl-2-propen-1-yl acetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methane | HCID 297 | — |
| Reactant | Benzene, (3-chloro-1-propenyl)- | HCID 94242 | — |
| Reactant | alpha-Benzyloxy[4-(acetoxymethyl)styrene] | HCID 21253608 | — |
| Reactant | alpha-Benzyloxy[3-(acetoxymethyl)styrene] | HCID 21253611 | — |
| Product | 3-Phenyl-2-propen-1-yl acetate | HCID 7660 | — |
Reaction Steps
α-Benzyloxy[4-(acetoxymethyl)styrene] and α-Benzyloxy[3-(acetoxymethyl)styrene] (Formula II, R1 =CH3COOCH2C6H4 -, R2 =benzyl). (Acetoxymethyl)styrene was prepared from (chloromethyl)styrene by the method described in Polymer, 1973, 14, 330. It was converted (Method C) to the required alkoxystyrene: 1H NMR (CCl4) δ 2.02 (3H, s), 4.23 (1H, d, J 2 Hz), 4.67 (1H, d, J 2 Hz), 4.87 (2H, s), 5.00 (2H, s), 7.0-7.7 (9H, m); MS (CH4) 283 (MH+, 1%), 91 (100%); IR 1740 cm-1.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05385996 |
| Source dataset | uspto-grants-1995_01 |
| ORD ID | ord-f41701d684504828b8f0cae76326cc52 |
| Source note | uspto-grants-1995_01 |