Sodium Chloride → HCID 53708905, compound

HRID 1770323Notes

Reaction equation

HRID 1770323 reaction equation
[CH2:1]([CH2:11][C:12](=[O:14])[CH3:13])/[CH:2]=[C:3](/[CH2:5][CH2:6][CH:7]=[C:8]([CH3:10])[CH3:9])\[CH3:4].[NH4+].[Cl-].[Na+].[Cl-].[CH3:19][O:20][C:21](=O)[O:22]C>>[O:14]=[C:12]([CH2:11][CH2:1][CH:2]=[C:3]([CH3:4])[CH2:5][CH2:6][CH:7]=[C:8]([CH3:9])[CH3:10])[CH2:13][C:21]([O:20][CH3:19])=[O:22]

Participants

5

Reactant 4

HCID 5234Sodium ChlorideHCID 12021Dimethyl CarbonateHCID 25517Ammonium ChlorideHCID 1549778Geranylacetone

Product 1

HCID 53708905HCID 53708905, compound

Procedure

The obtained mixture was heated to reflux (bath temperature 100°) then, during 1 h, there was added a solution of 0.5M of geranylacetone in 135 g (1.5M) of dimethylcarbonate, where upon the resulting reaction mixture was kept refluxing during 10 min. It was finally poured into a 10% aqueous solution of NH4Cl saturated with NaCl. An ether extraction, followed by the usual work up of the combined organic extracts and fractional distillation gave methyl 3-oxo-7,11-dimethyl-dodeca-6,10-dienoate.

Workup

  1. temperatureThe obtained mixture was heated
  2. temperatureto reflux (bath temperature 100°)
  3. customupon the resulting reaction mixture
  4. temperaturewas kept refluxing during 10 min
  5. extractionAn ether extraction
  6. distillationfollowed by the usual work up of the combined organic extracts and fractional distillation

Sources & evidence

ORD record
ord-10b3b6464767453490c0530ce0a36e43
Source dataset
uspto-grants-1995_01
Patent number
US05386039

Reaction notes

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