HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Hexene → 4,4-Dichloro-2-(2,5-dimethylphenyl)-4-siladecane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Hexene | HCID 11597 | — |
| Reactant | 3-(2,5-Dimethylphenyl)-1,1-dichloro-1-silabutane | HCID 14972039 | — |
| Catalyst | Chloroplatinic acid | HCID 61859 | — |
| Solvent | Isopropanol | HCID 3776 | — |
| Product | 4,4-Dichloro-2-(2,5-dimethylphenyl)-4-siladecane | HCID 20096052 | 65.7% |
Reaction Steps
In the same apparatus and procedures as EXAMPLE 1, 8.5 g (0.034 mole of 3-(2,5-dimethylphenyl)-1,1-dichloro-1-silabutane, 8.7 g (0.10 mole) of 1-hexene, and 120 μl of 1% chloroplatinic acid in isopropanol were placed and refluxed under the dry nitrogen atmosphere for 3 hours. Vacuum distillation of the reaction products gave 7.4 g (bp, 130°-3° C./0.6 mmHg) of 4,4-dichloro-2-(2,5-dimethylphenyl)-4-siladecane.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05386050 |
| Source dataset | uspto-grants-1995_01 |
| ORD ID | ord-31207eb48dac424db702211e135eebef |
| Source note | uspto-grants-1995_01 |