HuagongsheHuagongshe Chemistry Print Report · For research reference only
Styrene → 3,3-Dichloro-5-(2,5-dimethylphenyl)-1-phenyl-3-silahexane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Styrene | HCID 7501 | — |
| Reactant | 3-(2,5-Dimethylphenyl)-1,1-dichloro-1-silabutane | HCID 14972039 | — |
| Catalyst | Chloroplatinic acid | HCID 61859 | — |
| Solvent | Isopropanol | HCID 3776 | — |
| Product | 3,3-Dichloro-5-(2,5-dimethylphenyl)-1-phenyl-3-silahexane | HCID 20096047 | 78% |
Reaction Steps
In the same apparatus and procedure as EXAMPLE 1, 6.2 g (0.027 mole) of 3-(2,5-dimethylphenyl)-1,1-dichloro-1-silabutane, 5.4 g (0.05 mole) of styrene, and 90 μl of 1% chloroplatinic acid in isopropanol were placed and refluxed under the dry nitrogen atmosphere for 3 hours. Vacuum distillation of the reaction products gave 7.4 g (bp, 139°-141° C./0.6 mmHg) of 3,3-dichloro-5-(2,5-dimethylphenyl)-1-phenyl-3-silahexane.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05386050 |
| Source dataset | uspto-grants-1995_01 |
| ORD ID | ord-f3a496826b6b4456b5c40ba0d1b0e17c |
| Source note | uspto-grants-1995_01 |