Bis(4-methoxybenzyl)amine → HCID 57422340, compound

HRID 1770464Notes

Reaction equation

HRID 1770464 reaction equation
[CH3:1][O:2][C:3]1[CH:19]=[CH:18][C:6]([CH2:7][NH:8][CH2:9][C:10]2[CH:15]=[CH:14][C:13]([O:16][CH3:17])=[CH:12][CH:11]=2)=[CH:5][CH:4]=1.Cl[S:21]([C:24]1[CH:33]=[CH:32][C:27]([C:28]([O:30]C)=[O:29])=[CH:26][CH:25]=1)(=[O:23])=[O:22]>>[CH3:17][O:16][C:13]1[CH:14]=[CH:15][C:10]([CH2:9][N:8]([CH2:7][C:6]2[CH:5]=[CH:4][C:3]([O:2][CH3:1])=[CH:19][CH:18]=2)[S:21]([C:24]2[CH:25]=[CH:26][C:27]([C:28]([OH:30])=[O:29])=[CH:32][CH:33]=2)(=[O:23])=[O:22])=[CH:11][CH:12]=1

Participants

3

Reactant 2

HCID 714952Bis(4-methoxybenzyl)amineHCID 4738388Methyl 4-(Chlorosulfonyl)benzoate

Product 1

HCID 57422340HCID 57422340, compound

Procedure

Prepared as in example 5-27 from bis(4-methoxybenzyl)amine and methyl 4-(chlorosulfonyl)-benzoate (Example 5-10c). MS (M−H, 440.1); 1H NMR (400 MHz, DMSO-d6): δ, ppm: 3.68 (s, 6H), 4.20 (s, 4H), 6.77 (d, 4H, J=10 Hz), 6.98 (d, 4H, J=10 Hz), 7.92 (dd, 2H J=8 Hz), 8.06 (dd, 2H, J=8 Hz). Elemental analysis: (found): C, 62.45%; H, 5.19%; and N, 3.06%; (theoretical): C, 62.57%; H, 5.25%; and N, 3.17%;

Sources & evidence

ORD record
ord-b942e4f88a3e465290ee99cb852eec76
Source dataset
uspto-grants-2016_02
Patent number
US09247759B2

Reaction notes

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