Hexane → 1-Decene

To a 250 ml high pressure kettle for polymerization, 80 ml of n-hexane, 8 g of catalyst obtained as above, 30 ml of 1-decene and 0,159 ml of water as a co-catalyst are added. 1-decene oligomerization is carried out under a condition of a temperature of 80° C. and a pressure of 1.0 MPa for 5 hours, after which the reaction is stopped and the catalyst is filtered out, the solvent n-hexane is removed by distillation under ambient pressure, and then unreacted monomer 1-decene and part of the dimers are removed by distillation under reduced pressure to produce the final oligomer. The conversion of 1-decene is 52.4 wt %. The oligomer has a kinematic viscosity at 40° C. of 16.09 mm2/s, a kinematic viscosity at 100° C. of 5.38 mm2/s and a viscosity index of 208.85.

ORD record

ord-f18281ed98704953a16f0b585d676ef2

Source dataset

uspto-grants-2016_02

DOI

10.6084/m9.figshare.5104873.v1

Patent number

US09248430B2