HuagongsheHuagongshe Chemistry Print Report · For research reference only
6-Bromo-1-fluoronaphthalen-2-OL → HCID 57387164, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 6-Bromo-1-fluoronaphthalen-2-OL | HCID 11241940 | — |
| Reactant | 4-(Dihydroxyboranyl)-3-fluorobenzoic acid | HCID 23134177 | — |
| Product | HCID 57387164 | HCID 57387164 | — |
Reaction Steps
Followed the coupling procedure described in Example 29 starting from 6-bromo-1-fluoronaphthalen-2-ol (Intermediate 13) and 4-borono-3-fluorobenzoic acid. 1H-NMR (DMSO-d6, 300 MHz, TMS): δ 13.32 (b, 1H), 10.28 (b, 1H), 8.14 (s, 1H), 7.98 (d, 1H), 7.78 (d, 1H), 7.73-7.76 (m, 4H), 7.32 (t, 1H), MS (ESI): m/z=299.40 [M−1]−.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09249132B2 |
| Source dataset | uspto-grants-2016_02 |
| ORD ID | ord-d0219d71b1e440e6bb7a0a8b8752ccf2 |
| Source note | uspto-grants-2016_02 |