HCID 102189385, compound → HCID 102189388, compound

HRID 1775424Notes

Reaction equation

HRID 1775424 reaction equation
C1(SC2C3C=CC=CC=3SC=2I)C=CC=CC=1.[C:18]1([S:24][C:25]2[C:26]3[CH:38]=[C:37]4[C:32]([CH:33]=[CH:34][CH:35]=[CH:36]4)=[CH:31][C:27]=3[S:28][C:29]=2I)[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1>>[CH:23]1[C:18]2[S:24][C:25]3[C:26]4[CH:38]=[C:37]5[C:32]([CH:33]=[CH:34][CH:35]=[CH:36]5)=[CH:31][C:27]=4[S:28][C:29]=3[C:19]=2[CH:20]=[CH:21][CH:22]=1

Participants

3

Reactant 2

HCID 102189385HCID 102189385, compoundHCID 118193084HCID 118193084, compound

Product 1

HCID 102189388HCID 102189388, compoundYield 91%

Procedure

Except that 3-(phenylsulfenyl)-2-iodobenzo[b]thiophene was replaced with 3-(phenylsulfenyl)-2-iodonaphtho[2,3-b]thiophene, the reaction was implemented in the same way as in Example 3. Purification was implemented by column chromatography (silica gel, CHCl3, Rf: 0.9), so that a yellow solid was produced (yield: 91%).

Workup

  1. customPurification
  2. customwas produced (yield: 91%)

Sources & evidence

ORD record
ord-dc1f265f19db43148fba942d439deb86
Source dataset
uspto-grants-2016_02
Patent number
US09260451B2

Reaction notes

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