HCID 11046640, compound → HCID 131734741, compound

HRID 1775425Notes

Reaction equation

HRID 1775425 reaction equation
C1(SC2C3C=C4C(C=CC=C4)=CC=3SC=2[Si](C)(C)C)C=CC=CC=1.[C:25]1([Se:31][C:32]2[C:33]3[CH:44]=[CH:43][CH:42]=[CH:41][C:34]=3[S:35][C:36]=2[Si](C)(C)C)[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1>>[C:25]1([Se:31][C:32]2[C:33]3[CH:44]=[CH:43][CH:42]=[CH:41][C:34]=3[S:35][CH:36]=2)[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1

Participants

3

Reactant 2

HCID 11046640HCID 11046640, compoundHCID 123484518HCID 123484518, compound

Product 1

HCID 131734741HCID 131734741, compound

Procedure

Except that 3-(phenylsulfenyl)-2-trimethylsilylnaphtho[2,3-b]thiophene was replaced with 3-(phenylselenenyl)-2-trimethylsilylbenzo[b]thiophene, the reaction was implemented in the same way as in Example 8. Purification was implemented by column chromatography (silica gel, CHCl3, Rf: 0.9), so that a white solid was quantitatively produced.

Workup

  1. customPurification
  2. customwas quantitatively produced

Sources & evidence

ORD record
ord-864c03058fbe49898ec1d57d13e6a870
Source dataset
uspto-grants-2016_02
Patent number
US09260451B2

Reaction notes

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