HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-Bromothiophene → 3-Hexylthiophene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-Bromothiophene | HCID 13383 | — |
| Reactant | HCID 178444609 | HCID 178444609 | — |
| Product | 3-Hexylthiophene | HCID 566849 | — |
Reaction Steps
In the presence of 0.0012 eq. of [1,3-bis(diphenylphosphine)propane]dichloronickel (II) (Ni(dppp)Cl2) catalyst, 1.3 eq. of hexylmagnesium bromide (Hexyl-MgBr) is added to 3-bromothiophene monomer to obtain 3-hexylthiophene, and then 2 eq. of N-bromosuccimide (NBS) is further added thereto to obtain 2,5-dibromo-3-hexylthiophene monomer.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09260572B2 |
| Source dataset | uspto-grants-2016_02 |
| ORD ID | ord-5c33268f39f54d1dbb78f9fb27499bba |
| Source note | uspto-grants-2016_02 |