1-Iododecane → HCID 53732894, compound

HRID 1776059Notes

Reaction equation

HRID 1776059 reaction equation
[CH3:1][O:2][C:3](=[O:12])[CH2:4][C:5]1[CH:10]=[CH:9][C:8]([OH:11])=[CH:7][CH:6]=1.I[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH3:23]>>[CH3:1][O:2][C:3](=[O:12])[CH2:4][C:5]1[CH:10]=[CH:9][C:8]([O:11][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH3:23])=[CH:7][CH:6]=1

Participants

3

Reactant 2

HCID 163141-IododecaneHCID 518900Benzeneacetic acid, 4-hydroxy-, methyl ester

Product 1

HCID 53732894HCID 53732894, compound

Procedure

First, a dibenzyl ketone having the alkoxy (OC10H21) groups is prepared to produce the polyphenylene (a). Specifically, 4-hydroxybenzeneacetic acid methyl ester is reacted with 1-iododecane to obtain 4-decyloxybenzeneacetic acid methyl ester as shown in the following reaction formula (32).

Sources & evidence

ORD record
ord-e240c08f6db24277a08a241360829b58
Source dataset
uspto-grants-2016_02
Patent number
US09263688B2

Reaction notes

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