Carbazole → Carbazole

HRID 1776067Notes

Reaction equation

HRID 1776067 reaction equation
[C:1]1([C:7]2[CH:8]=[CH:9][C:10]3[N:11]([C:26]4[CH:27]=[C:28]([CH:39]=[CH:40][CH:41]=4)[O:29][CH2:30]CCCCCCCS)[C:12]4[C:17]([C:18]=3[CH:19]=2)=[CH:16][C:15]([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)=[CH:14][CH:13]=4)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C1C2NC3C(=CC=CC=3)C=2C=CC=1>>[CH:9]1[C:10]2[NH:11][C:12]3[C:17](=[CH:16][CH:15]=[CH:14][CH:13]=3)[C:18]=2[CH:19]=[CH:7][CH:8]=1.[C:1]1([C:7]2[CH:8]=[CH:9][C:10]3[N:11]([C:26]4[CH:41]=[CH:40][CH:39]=[C:28]([O:29][CH3:30])[CH:27]=4)[C:12]4[C:17]([C:18]=3[CH:19]=2)=[CH:16][C:15]([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)=[CH:14][CH:13]=4)[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

4

Reactant 2

HCID 6854CarbazoleHCID 58078016HCID 58078016, compound

Product 2

HCID 6854CarbazoleHCID 66717081HCID 66717081, compound

Procedure

A colorless viscous matter of 8-[3-(3,6-diphenylcarbazole-9-yl)phenoxy]octane-1-thiol (C-4) (hereinafter referred to as carbazole derivative 6) represented by the chemical structure 12 is obtained in the same manner as in preparation of Carbazole Derivative 1 except that 3,6-diphenyl-9-(3-methoxyphenyl)carbazole is used instead of 3,6-bis(5-methylthiophene-2-yl)-9-(4-methoxyphenyl)carbazole (B-2).

Sources & evidence

ORD record
ord-f14941cb3d8e46429041d20741b27124
Source dataset
uspto-grants-2016_02
Patent number
US09263682B2

Reaction notes

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