Chloroform → HCID 86641263, compound

HRID 1779127Notes

Reaction equation

HRID 1779127 reaction equation
[CH2:1]([N:9]1[C:13](=[O:14])[CH:12]=[CH:11][C:10]1=[O:15])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[C:16]1(=[O:22])[O:21][C:19](=[O:20])[CH:18]=[CH:17]1.COC(=O)C(N=NC(C)(C)C(OC)=O)(C)C.C(Cl)(Cl)Cl>CO>[CH2:1]([N:9]1[C:10](=[O:15])[CH:11]=[CH:12][C:13]1=[O:14])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[C:19]1(=[O:20])[O:21][C:16](=[O:22])[CH:17]=[CH:18]1

Participants

6

Reactant 4

HCID 6212ChloroformHCID 7923Maleic AnhydrideHCID 757631,1'-Dimethyl 2,2'-(1,2-diazenediyl)bis(2-methylpropanoate)HCID 512829Octyl Maleimide

Product 1

HCID 86641263HCID 86641263, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

Into a sealed glass tube were introduced 26 g of N-n-octylmaleimide, 2.4 g of maleic anhydride, and 0.036 g of dimethyl-2,2′-azobisisobutyrate as a polymerization initiator. After nitrogen displacement, a radical polymerization reaction was conducted under the conditions of a polymerization temperature of 60° C. and a polymerization time of 5 hours. Chloroform was added after the reaction to obtain a polymer solution. Thereafter, this solution was mixed with excess methanol to thereby precipitate the polymer. The polymer obtained was taken out by filtration, subsequently sufficiently washed with methanol, and dried at 80° C. Thus, an N-n-octylmaleimide-maleic anhydride copolymer resin was obtained in an amount of 19 g. The N-n-octylmaleimide-maleic anhydride copolymer resin obtained contained a maleic anhydride residue in an amount of 20% by weight and had a number-average molecular weight of 120,000.

Workup

  1. customAfter nitrogen displacement, a radical polymerization reaction
  2. customwas conducted under the conditions of a polymerization temperature of 60° C.
  3. customa polymerization time of 5 hours
  4. customafter the reaction
  5. customto obtain a polymer solution
  6. customto thereby precipitate the polymer
  7. customThe polymer obtained
  8. filtrationwas taken out by filtration
  9. washsubsequently sufficiently washed with methanol
  10. customdried at 80° C

Sources & evidence

ORD record
ord-65c591006dec4d87a2cbd574dd98be6a
Source dataset
uspto-grants-2016_02
Patent number
US09268076B2

Reaction notes

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