HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → 6-Butylbenzo[b]quinolizinium perchlorate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Sodium Perchlorate | HCID 522606 | — |
| Reactant | 1-Methoxybenzo[b]quinolizinium perchlorate | HCID 15186287 | — |
| Solvent | Hydrogen Bromide | HCID 260 | — |
| Product | 6-Butylbenzo[b]quinolizinium perchlorate | HCID 19047476 | 156.2% |
Reaction Conditions
| Temperature | 100 °C |
|---|
Reaction Steps
A mixture of 1-methoxybenzo[b]quinolizinium perchlorate (1.4 g; 6.1 mmol) in 30 ml of 48% HBr was heated at 100° C. for 16 hour. The reaction mixture was poured into 100 ml of water and 50 ml of sodium perchlorate was added with stirring. The resulting solid was filtered and dried to afford 1.6 g (88.8%) of 1-hydroxybenzo[b]quinolizinium perchlorate (Formula II: R1 =1-OH; R2 =R3 =H; X- =ClO4-) as a solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05631264 |
| Source dataset | uspto-grants-1997_05 |
| ORD ID | ord-026656cf16884d9aa661211bb77daa46 |
| Source note | uspto-grants-1997_05 |