HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Methyl-4-nitro-1-phenoxybenzene → 3-Methyl-4-phenoxyaniline
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Methyl-4-nitro-1-phenoxybenzene | HCID 18616691 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | 3-Methyl-4-phenoxyaniline | HCID 15550488 | — |
Reaction Steps
The nitro compound prepared above was reduced under H2 using 10% Pd/C catalyst in MeOH to give 3-methyl-4-phenoxyaniline. 1H NMR (CDCl3) δ 7.27 (m, 2H), 6.97 (m, 1H), 6.83 (m, 2H), 6.80 (d, 1H), 6.60 (d, 1H), 6.52 (m, 1H), 3.53 (br s, 2H), 2.11 (s, 3H). MS (DCl/NH3) m/e 200 (M+H)+, 217 (M+H+NH3)+.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05631401 |
| Source dataset | uspto-grants-1997_05 |
| ORD ID | ord-bf5fec9254e74095aecd364f22ab9d66 |
| Source note | uspto-grants-1997_05 |