Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Tributylstannane | HCID 5948 | — |
| Reactant | HCID 22872936 | HCID 22872936 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 54240069 | HCID 54240069 | 135.5% |
Reaction Steps
1,2,4,6-tetra-O-acetyl-3-O-phenylthiono-glucopyranose (5.2 g) was dissolved in toluene (50 mL) and added to tributyl tin hydride (6.7 mL) and azobisisobutryonitrile (2.8 g). The reaction mixture was heated for 1 to 3 hours at 80° C. to provide for 3-deoxy-2,4,6-tri-O-acetyl-glucopyranose (4.5 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US05633233 |
|---|
| Source dataset | uspto-grants-1997_05 |
|---|
| ORD ID | ord-32ce6edd6bef4c65ac649d1e55c8191a |
|---|
| Source note | uspto-grants-1997_05 |
|---|
