Sulfamic acid[[2,6-bis(1-methylethyl)phenyl]-acetyl]-2,6-bis(1-methylethyl)phenyl ester → Sulfamic acid[1-oxo-3-[2,4,6-tris(1-methylethyl)phenyl]-2-propenyl]-2,6-bis(1-methylethyl)phenyl ester

HRID 1781486Notes

Reaction equation

HRID 1781486 reaction equation
CC(C1C=CC=C(C(C)C)C=1CC([C:16]1[C:17]([CH:30]([CH3:32])[CH3:31])=[C:18]([O:25][S:26](=[O:29])(=[O:28])[NH2:27])[C:19]([CH:22]([CH3:24])[CH3:23])=[CH:20][CH:21]=1)=O)C.C(C1C=CC=C(C(C)C)[C:37]=1[CH2:45][C:46](O)=[O:47])(C)C.[CH3:49][CH:50]([C:52]1[CH:57]=[C:56]([CH:58]([CH3:60])[CH3:59])[CH:55]=[C:54]([CH:61]([CH3:63])[CH3:62])[C:53]=1C=CCC(O)=O)[CH3:51]>>[O:47]=[C:46]([C:16]1[C:17]([CH:30]([CH3:32])[CH3:31])=[C:18]([O:25][S:26](=[O:28])(=[O:29])[NH2:27])[C:19]([CH:22]([CH3:24])[CH3:23])=[CH:20][CH:21]=1)[CH:45]=[CH:37][C:53]1[C:54]([CH:61]([CH3:63])[CH3:62])=[CH:55][C:56]([CH:58]([CH3:59])[CH3:60])=[CH:57][C:52]=1[CH:50]([CH3:49])[CH3:51]

Participants

4

Reactant 3

HCID 10226443Sulfamic acid[[2,6-bis(1-methylethyl)phenyl]-acetyl]-2,6-bis(1-methylethyl)phenyl esterHCID 152779902-(2,6-Diisopropylphenyl)acetic acidHCID 538822253-[2,4,6-Tris-(1-methylethyl)phenyl]-2-propenyl carboxylic acid

Product 1

HCID 54444708Sulfamic acid[1-oxo-3-[2,4,6-tris(1-methylethyl)phenyl]-2-propenyl]-2,6-bis(1-methylethyl)phenyl ester

Procedure

This compound was prepared in the same manner as for the title compound of Example 1, except that 2,6-diisopropylphenylacetic acid was replaced with 3-[2,4,6-tris(1-methylethyl)phenyl]-2-propenyl carboxylic acid, mp 144°-148° C.

Sources & evidence

ORD record
ord-5f2251d192ef4cac9dbfd2f584ab989b
Source dataset
uspto-grants-1997_05
Patent number
US05633287

Reaction notes

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