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Hexafluoropropene oxide trimer → CF3(CF2)2Ocf(CF3)CF2ocf(CF3)cooch2CH(CH3)O(CH2)3ococf(CF3)-ocf2CF(CF3)O(CF2)2CF3
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hexafluoropropene oxide trimer | HCID 102863 | — |
| 反応物 | 2-(3-Hydroxypropoxy)propan-1-ol | HCID 21758503 | — |
| 溶媒 | Sodium Bicarbonate | HCID 516892 | — |
| 生成物 | CF3(CF2)2Ocf(CF3)CF2ocf(CF3)cooch2CH(CH3)O(CH2)3ococf(CF3)-ocf2CF(CF3)O(CF2)2CF3 | HCID 131726696 | — |
反応手順
CF3(CF2)2OCF(CF3)CF2OCF(CF3)COF (120.69 g) was loaded into an autoclave and stirred under a nitrogen stream, and HO(CH2)3OCH(CH3)CH2OH (15.1 g) prepared in Example 2-3 was fed over 2 hours, while the temperature in the autoclave was maintained at 30° C. or below. Then, the reaction solution was stirred at room temperature under a nitrogen stream overnight and poured onto saturated aqueous NaHCO3 (500 mL) with ice.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07501540B2 |
| 出典データセット | uspto-grants-2009_03 |
| ORD ID | ord-c4229ab0dce14b9886f55da78a21d461 |
| 出典メモ | uspto-grants-2009_03 |