HRID1784327

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6854

Carbazole

C12H9N

HCID631855

3,6-Dibromo-9-ethylcarbazole

C14H11Br2N

HCID2802035

N-benzyl-3,6-dibromocarbazole

C19H13Br2N

PRODUCTS

生成物

结构：c1ccc(Cn2c3ccc(-n4c5ccccc5c5ccccc54)cc3c3cc(-n4c5ccccc5c5ccccc54)ccc32)cc1

HCID68880940

未命名化合物

收率 70%

PROCEDURE

实验过程

The obtained N-benzyl-3,6-dibromocarbazole was allowed to couple with carbazole in the same manner as described in synthesis of N-ethyl-3,6-dibromocarbazole (Embodiment 1) to give N-benzyl-3,6-di(N-carbazolyl)carbazole. The yield was 70%.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-b8fd5a045a774095917e7a6e7df679dd
来源数据集: uspto-grants-2009_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US07504162B2
来源说明: uspto-grants-2009_03

反应 SMILES

[CH2:1]([N:8]1[C:20]2[CH:19]=[CH:18][C:17](Br)=[CH:16][C:15]=2[C:14]2[C:9]1=[CH:10][CH:11]=[C:12](Br)[CH:13]=2)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH:23]1[C:35]2[NH:34][C:33]3[C:28](=[CH:29][CH:30]=[CH:31][CH:32]=3)[C:27]=2[CH:26]=[CH:25][CH:24]=1.C([N:38]1[C:50]2[CH:49]=[CH:48][C:47](Br)=[CH:46][C:45]=2[C:44]2[C:39]1=[CH:40][CH:41]=[C:42](Br)[CH:43]=2)C>>[CH2:1]([N:8]1[C:20]2[CH:19]=[CH:18][C:17]([N:34]3[C:33]4[CH:32]=[CH:31][CH:30]=[CH:29][C:28]=4[C:27]4[C:35]3=[CH:23][CH:24]=[CH:25][CH:26]=4)=[CH:16][C:15]=2[C:14]2[C:9]1=[CH:10][CH:11]=[C:12]([N:38]1[C:50]3[CH:49]=[CH:48][CH:47]=[CH:46][C:45]=3[C:44]3[C:39]1=[CH:40][CH:41]=[CH:42][CH:43]=3)[CH:13]=2)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1