Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Isopropanol | HCID 3776 | — |
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Reactant | Diisopropyl diazene-1,2-dicarboxylate | HCID 75555 | — |
| Reactant | HCID 68831940 | HCID 68831940 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Solvent | Dichloromethane methanol | HCID 21226129 | — |
| Product | HCID 57592484 | HCID 57592484 | — |
Reaction Steps
The phenol (D6) (1.1 g), triphenylphosphine (1.7 g) and isopropanol (0.5 ml) were dissolved in tetrahydrofuran and cooled to 0° C., Diisopropyl azodicarboxylate (1.3 ml) was added dropwise and the mixture stirred at room temperature for 1 h. The mixture was passed through an SCX column and then chromatography on silica eluting with 4% methanol/dichloromethane afforded the titled compound D29 (870 mg) MH+ 365
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US07504392B2 |
|---|
| Source dataset | uspto-grants-2009_03 |
|---|
| ORD ID | ord-cab4f33480a74a2e8c8345aa89758166 |
|---|
| Source note | uspto-grants-2009_03 |
|---|
