2-(Methylthio)benzeneboronic acid → HCID 18444601, compound

HRID 1786599Notes

Reaction equation

HRID 1786599 reaction equation
C[O:2][C:3]([C:5]1[O:6][C:7]([CH3:19])=[C:8]([CH2:10][O:11][C:12]2[CH:17]=[CH:16][C:15](I)=[CH:14][CH:13]=2)[CH:9]=1)=[O:4].[CH3:20][S:21][C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][C:23]=1B(O)O>>[CH3:19][C:7]1[O:6][C:5]([C:3]([OH:2])=[O:4])=[CH:9][C:8]=1[CH2:10][O:11][C:12]1[CH:17]=[CH:16][C:15]([C:23]2[CH:24]=[CH:25][CH:26]=[CH:27][C:22]=2[S:21][CH3:20])=[CH:14][CH:13]=1

Participants

3

Reactant 2

HCID 27735432-(Methylthio)benzeneboronic acidHCID 588241574-(4-Iodo-phenoxymethyl)-5-methyl-furan-2-carboxylic acid methyl ester

Product 1

HCID 18444601HCID 18444601, compound

Procedure

Compound (105) was prepared from compound (20) and (2-methylsulphanyl-phenyl)-boronic acid by adapting the procedure of Example 5(b). LC/MS System B; Rt=1.86 mins, m/z (ES−)=353 (M−H for C20H18O4S).

Sources & evidence

ORD record
ord-01bea476d7a24691adbcc38b526e3118
Source dataset
uspto-grants-2009_03
Patent number
US07507754B2

Reaction notes

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