HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Piperazinecarboxaldehyde → HCID 178521668, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Piperazinecarboxaldehyde | HCID 82191 | — |
| Reactant | 2,3-Epoxy-2,3-dihydro-1,4-naphthoquinone | HCID 85844 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 178521668 | HCID 178521668 | — |
Reaction Steps
A mixture of 3.48 g of 2,3-epoxy-2,3-dihydro-1,4-naphthoquinone, 2.28 of 1-piperazinecarboxaldehyde and 200 ml of absolute ethanol was stirred for 20 hours, then concentrated to one-half its original volume and refrigerated overnight. The solid was collected and recrystallized from dichloromethane/ethanol, giving 2.65 g of the desired product, mp 200°-203° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04686220 |
| Source dataset | uspto-grants-1987_08 |
| ORD ID | ord-76e2664d978c4a2197ffbdd9fcee90d3 |
| Source note | uspto-grants-1987_08 |