Acetic Acid → 7-Acetoxy-2-(5-methoxyhept-1-y)bicyclo[3.3.0]octane
Reaction equation
[CH3:1][O:2][CH:3]([CH2:17][CH3:18])[CH2:4][CH2:5][CH2:6][CH2:7][CH:8]1[CH2:15][CH2:14][CH:13]2[CH:9]1[CH2:10][CH:11]([OH:16])[CH2:12]2.[C:19](O)(=[O:21])[CH3:20]>>[C:19]([O:16][CH:11]1[CH2:10][CH:9]2[CH:13]([CH2:14][CH2:15][CH:8]2[CH2:7][CH2:6][CH2:5][CH2:4][CH:3]([O:2][CH3:1])[CH2:17][CH3:18])[CH2:12]1)(=[O:21])[CH3:20]Participants
3
Procedure
The procedure followed is the same as that described in Example 24 substituting 2-(5-methoxyhept-1-yl)bicyclo[3.3.0]-7octanol {octahydro-4-(5-methoxyheptyl)-2-pentalenol} (1.0 g, 4.0 mmoles), and glacial acetic acid (7 ml). The product is kugelrohred under reduced pressure leaving a clear, colorless oil (0.7 g, 2.5 mmoles).
Sources & evidence
- ORD record
- ord-8925cec102084632920e4fddf72535c1
- Source dataset
- uspto-grants-1987_08
- Patent number
- US04689345
Reaction notes
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