HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sulfuric acid magnesium salt (1:1) → 2-Methylideneadamantane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sulfuric acid magnesium salt (1:1) | HCID 24083 | — |
| Reactant | 2-Methyl-2-adamantyl methacrylate | HCID 9837566 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | 2-Methylideneadamantane | HCID 136684 | — |
Reaction Steps
A reaction was conducted at a refluxing temperature for 3 hours using no magnesium sulfate but using a Dean-Stark dehydrating apparatus. Toluene was used as a solvent. The other operating conditions were the same as in Example 16, and a reaction, a post-treatment, etc. were conducted. 1.0 g of a crude product was obtained. However, the purity of 2-methyl-2-adamantyl methacrylate in the crude product was 15% and 2-methyleneadamantane was formed by 80%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07071352B2 |
| Source dataset | uspto-grants-2006_07 |
| ORD ID | ord-a2b58a8b0a4645b499a57b5d1f4c1794 |
| Source note | uspto-grants-2006_07 |