HuagongsheHuagongshe Chemistry Print Report · For research reference only
Pentyltriphenylphosphonium bromide → 2-(1-(1-Hexenyl)cyclopropyl]-2-methyl-1,3-dioxolan
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Pentyltriphenylphosphonium bromide | HCID 2724565 | — |
| Reactant | 1-(2-Methyl-1,3-dioxolan-2-YL)cyclopropane-1-carbaldehyde | HCID 14375557 | — |
| Product | 2-(1-(1-Hexenyl)cyclopropyl]-2-methyl-1,3-dioxolan | HCID 69650419 | — |
Reaction Steps
2.07 g of pentyltriphenylphosphonium bromide and 600 mg of aldehyde 7 are reacted analogously to 193., and 567 g of title substance 200 is obtained as a colorless oil (8:1 E,Z-mixture that cannot be separated).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07071344B1 |
| Source dataset | uspto-grants-2006_07 |
| ORD ID | ord-5c74e7f546924d35934b1d90c6516f3d |
| Source note | uspto-grants-2006_07 |