HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phosphonium, hexyltriphenyl-, bromide (1:1) → 2-(1-(1-Heptenyl)cyclopropyl]-2-methyl-1,3-dioxolan
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phosphonium, hexyltriphenyl-, bromide (1:1) | HCID 2724569 | — |
| Reactant | 1-(2-Methyl-1,3-dioxolan-2-YL)cyclopropane-1-carbaldehyde | HCID 14375557 | — |
| Product | 2-(1-(1-Heptenyl)cyclopropyl]-2-methyl-1,3-dioxolan | HCID 69650417 | — |
Reaction Steps
1.93 g of hexyltriphenylphosphonium bromide and 900 mg of aldehyde 7 are reacted analogously to 193., and 879 mg of title substance 203 is obtained as a colorless oil (1:3 E,Z mixture that cannot be separated).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07071344B1 |
| Source dataset | uspto-grants-2006_07 |
| ORD ID | ord-d3b3811c49ec430b9bcb1f0aa72e085a |
| Source note | uspto-grants-2006_07 |