HuagongsheHuagongshe Chemistry Print Report · For research reference only
Heptyltriphenylphosphonium bromide → (Z)-2-Methyl-2-[1-(1-octenyl)cyclopropyl]-1,3-dioxolan
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Heptyltriphenylphosphonium bromide | HCID 2724567 | — |
| Reactant | 1-(2-Methyl-1,3-dioxolan-2-YL)cyclopropane-1-carbaldehyde | HCID 14375557 | — |
| Product | (Z)-2-Methyl-2-[1-(1-octenyl)cyclopropyl]-1,3-dioxolan | HCID 69650424 | — |
Reaction Steps
4.87 g of heptyltriphenylphosphonium bromide and 1.25 g of aldehyde 7 are reacted analogously to 193., and 978 mg of title substance 206 is obtained as a colorless oil (only Z-isomer).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07071344B1 |
| Source dataset | uspto-grants-2006_07 |
| ORD ID | ord-72ef0d959b81425ab540df2aa60f8e0a |
| Source note | uspto-grants-2006_07 |